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Miscibility is the ability of two liquids to mix and form a homogeneous solution. Here's a breakdown of the miscibility of the pairs based on their polarities:
a. Water and Ethanol:
Water: Polar molecule due to its bent shape and electronegative oxygen atom.
Ethanol: Polar molecule with a hydroxyl (-OH) group, which forms hydrogen bonds with water.
Result: Miscible. Water and ethanol are both polar and can form strong hydrogen bonds, leading to easy mixing.
b. Water and Hexane:
Water: Polar (explained above).
Hexane: Nonpolar hydrocarbon chain.
Result: Immiscible. Water and hexane have very different polarities. Water cannot form significant interactions with the nonpolar hexane molecules, leading to separation.
c. Hexane and Ethanol:
Hexane: Nonpolar (explained above).
Ethanol: Polar (explained above).
Result: Partially miscible. Ethanol's polar -OH group can interact weakly with hexane, resulting in some degree of mixing. However, the nonpolar hydrocarbon chain dominates, leading to limited miscibility.