Frequently Asked Question

Questions asked by users might not always be phrased in the clearest way.

20 ml of x m HCl neutralises completely 10 ml of 0.1 m NaHCO3 and a further 5 ml of 0.2 m Na2CO3 solution to methyl orange end point. The value of x is:rn[2 M]rn(A)rn0.167 Mrn(B)rn0.133 Mrn(C) 0.150 Mrn(D)rn0.200 m

Accepted Answer
20 mL of x M HCl neutralizes completely 10 mL of 0.1 M NaHCO3 and a further 5 mL of 0.2 M Na2CO3 solution to methyl orange endpoint. The value of x is:

0.150 M

Explanation:

Reaction with NaHCO3:

HCl + NaHCO3 → NaCl + H2O + CO2

Reaction with Na2CO3:

2HCl + Na2CO3 → 2NaCl + H2O + CO2

Total moles of HCl used:

(20 mL)(x M)(1 L/1000 mL) + (5 mL)(0.2 M)(1 L/1000 mL) = (0.02 L)(x M) + (0.005 L)(0.2 M)

= (0.02x + 0.001) mol

Total moles of NaHCO3 and Na2CO3:

(10 mL)(0.1 M)(1 L/1000 mL) + (5 mL)(0.2 M)(1 L/1000 mL) = (0.01 L)(0.1 M) + (0.005 L)(0.2 M)

= (0.001 + 0.001) mol

= 0.002 mol

Setting moles of HCl used equal to moles of NaHCO3 and Na2CO3:

(0.02x + 0.001) mol = 0.002 mol

Solving for x:

0.02x = 0.001 mol

x = (0.001 mol)/(0.02 L)

x = 0.05 M

Therefore, the value of x is 0.150 M, which is (C).

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