Frequently Asked Question

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Diamagnetic correction calculation for Jeff in [co(ox)3]4-

Accepted Answer

Diamagnetic correction is a factor used in magnetic susceptibility measurements to account for the diamagnetic contributions of all the atoms in a molecule. This is particularly important for determining the spin-only magnetic moment of transition metal complexes like [Co(ox)3]4-, where paramagnetic behavior is expected.
To calculate the diamagnetic correction for [Co(ox)3]4-, you'd need to sum the individual atomic diamagnetic susceptibilities of all the atoms in the complex. This would involve looking up the diamagnetic susceptibilities of cobalt, oxygen, and carbon atoms in a standard reference like the Pascal's constants table.


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