Frequently Asked Question

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Give all term symbols of an atom with configuration s^1p^1 with working

Accepted Answer

The term symbols for an atom with configuration s¹p¹ are:
1. ³P (triplet P)
2. ¹P (singlet P)
Working:

Determining the total spin angular momentum (S):

s¹: One electron with spin s = 1/2

p¹: One electron with spin s = 1/2

Total spin angular momentum (S) can be S = s₁ + s₂ = 1/2 + 1/2 = 1 or S = s₁ - s₂ = 1/2 - 1/2 = 0

Therefore, S = 1 or S = 0

Determining the total orbital angular momentum (L):

s¹: l = 0

p¹: l = 1

Total orbital angular momentum (L) = l₁ + l₂ = 0 + 1 = 1

Calculating the multiplicity (2S+1):

For S = 1, Multiplicity = 2(1)+1 = 3 (triplet)

For S = 0, Multiplicity = 2(0)+1 = 1 (singlet)

Determining the term symbol:

The term symbol is written as (2S+1)L, where L is represented by:

L = 0, S

L = 1, P

L = 2, D

L = 3, F

etc.

Therefore, the term symbols are ³P (triplet P) and ¹P (singlet P).


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