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To calculate the effective nuclear charge (Ueff) for [Co(ox)3]^4-, you would need to consider the following factors:
1. The atomic number of cobalt (Co): This tells you the number of protons in the cobalt nucleus, which is 27.
2. The shielding effect of the electrons: The electrons in the inner shells of the cobalt atom shield the outer electrons from the full attraction of the nucleus. This effect is not straightforward to calculate, but it can be estimated using Slater's rules.
3. The charge of the complex ion: The 4- charge on the complex ion means that the cobalt atom has lost 4 electrons, making it more attractive to the remaining electrons.
To get a more accurate estimate of Ueff, you would need to use a computational chemistry approach. However, a simplified calculation can be done using Slater's rules, which provides a reasonable approximation of Ueff.