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These compounds are fascinating examples of inorganic chemistry! Here's a concise overview of their properties and structures:
Boranes & Carboranes
Structure: Boranes (BnHn) are electron-deficient clusters containing boron and hydrogen. Carboranes incorporate carbon atoms into the borane framework.
Properties: Highly reactive, often flammable, and exhibit unusual bonding patterns involving three-center two-electron bonds (B-H-B).
Borazines
Structure: Cyclic compounds analogous to benzene, with alternating boron and nitrogen atoms.
Properties: Aromatic character, planar structure, and often used as precursors for various materials.
Silicates
Structure: Contain silicon and oxygen, forming complex structures like tetrahedral SiO4 units. These units can link together to form chains, sheets, or three-dimensional frameworks.
Properties: Widely occurring in minerals and rocks, often used in glass and ceramic production.
Carbides
Structure: Composed of carbon and another element. They can be ionic (like CaC2), covalent (like SiC), or interstitial (like Fe3C).
Properties: Vary widely based on the bonding type. Some are hard and refractory, while others are used as catalysts or for synthesis.
Sulphur-Nitrogen Compounds
Structure: These compounds involve S-N bonds and often exhibit cyclic or cage-like structures.
Properties: Many are highly reactive and explosive. Some, like S4N4, are important precursors for other sulfur-nitrogen compounds.
For further study, you can explore these topics using keywords like:
Boranes, Carboranes, Boron hydrides
Borazines, Inorganic aromatics
Silicates, Silicate minerals, Zeolites
Carbides, Silicon carbide, Tungsten carbide
Sulfur-nitrogen compounds, S4N4, Polythiazyl