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The intensity of a UV-Vis peak is related to the strength of the metal-ligand bond and the number of d electrons in the metal ion. However, ranking transition metals based solely on peak intensity is a complex task. Here's why:
Ligand Field Strength: Water is a weak field ligand, meaning it doesn't strongly affect the d orbital splitting. This makes predicting peak intensities challenging.
Electronic Configuration: The number of d electrons in the transition metal significantly impacts peak intensity. However, the trend isn't always straightforward.
Spin Selection Rules: Transitions are governed by spin selection rules, which can influence peak intensity.
To accurately rank transition metals based on peak intensity, you would need to consider each metal's specific electronic configuration, the ligand field strength of water, and the spin selection rules for each transition. This requires detailed spectroscopic analysis, not just a simple ranking.