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What does electronic spectra of a transition metal complex mean?

Accepted Answer

The electronic spectra of a transition metal complex refers to the pattern of absorption and emission of light by the complex. This pattern is determined by the electronic transitions within the metal ion, influenced by the ligands surrounding it. The d-orbitals of the metal ion are split into different energy levels by the ligand field, and the energy difference between these levels corresponds to specific wavelengths of light. When a photon of light with the right energy is absorbed, an electron is promoted from a lower energy d-orbital to a higher one, giving rise to characteristic absorption bands in the visible or UV region. This spectrum can provide information about the metal ion, the ligands, and the coordination geometry of the complex.


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