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Questions asked by users might not always be phrased in the clearest way.
In the sentence "The reactions with diethylamine and benzylamine are moderately exothermic and take ca. 30 min", "ca. 30 min" refers to the approximate time required for the reaction to complete. The "ca." is an abbreviation for "circa", meaning 'around' or 'approximately'. So, the reaction takes roughly 30 minutes.