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Using Boyle's Law, which states that P₁V₁ = P₂V₂, we can calculate the final pressure (P₂) of the refrigerant. Given that the initial volume (V₁) is 0.25 L, the initial pressure (P₁) is 585 mmHg, and the final volume (V₂) is 1.00 L, we have:
P₁V₁ = P₂V₂
585 mmHg * 0.25 L = P₂ * 1.00 L
P₂ = (585 mmHg * 0.25 L) / 1.00 L
P₂ = 146.25 mmHg
Therefore, the final pressure of the refrigerant when its volume is increased to 1.00 L will be 146.25 mmHg.