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Reaction between a tertiary amine and H2O2 explained step by step
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Tertiary amines, unlike primary and secondary amines, do not readily react with hydrogen peroxide (H₂O₂). Here's why:
Oxidation: H₂O₂ is a common oxidizing agent. It typically oxidizes primary and secondary amines by attacking the nitrogen atom, forming N-oxides. Tertiary amines lack a hydrogen atom directly attached to the nitrogen, making them resistant to this oxidation process.
Steric Hindrance: The bulky alkyl groups surrounding the nitrogen in a tertiary amine create significant steric hindrance, making it difficult for the H₂O₂ molecule to approach and react with the nitrogen atom.
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