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For an octahedral d³ complex, the UV-Vis spectrum is dominated by transitions from the ground state, ³T₁g, to excited states, specifically to the ³T₂g and ³A₂g states. These transitions are d-d transitions, meaning they involve the promotion of electrons from lower energy d orbitals to higher energy d orbitals. The specific transitions observed depend on the ligand field strength and the nature of the metal ion.