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Both Toluene and Nitrobenzene are more reactive than Benzene. Toluene is more reactive due to the presence of a methyl group, which donates electrons to the ring, making it more reactive towards electrophilic aromatic substitution reactions. Nitrobenzene, on the other hand, is more reactive due to the presence of a nitro group, which withdraws electrons from the ring, making it more reactive towards nucleophilic aromatic substitution reactions.