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Which species is unstable with respect to disproportionation a frost diagram for sulphur in basic solution

Accepted Answer

In a basic solution, the species sulfite (SO3^2-) is unstable with respect to disproportionation. This can be seen on a Frost diagram for sulfur in basic solution where the line connecting sulfite to sulfide (S^2-) and sulfate (SO4^2-) has a negative slope, indicating a thermodynamically favorable disproportionation reaction.


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