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1.00 mole of H2SO4 contains the largest number of atoms. Here's why:
Avogadro's Number: One mole of any substance contains 6.022 x 10^23 particles (atoms, molecules, etc.).
Atoms per Molecule:
H2SO4 (sulfuric acid): 2 hydrogen + 1 sulfur + 4 oxygen = 7 atoms per molecule
KCl (potassium chloride): 1 potassium + 1 chlorine = 2 atoms per molecule
NH3 (ammonia): 1 nitrogen + 3 hydrogen = 4 atoms per molecule
HBr (hydrogen bromide): 1 hydrogen + 1 bromine = 2 atoms per molecule
Since 1 mole of H2SO4 has the most atoms per molecule (7), and all the moles are equal, it will have the largest total number of atoms.