Primary Reference Electrode (PRE)
* Standard potential is accurately known.
* Potential is highly reproducible and stable.
* Hydrogen electrode is the most common PRE.
* Used for calibrating other electrodes and measuring pH.
Secondary Reference Electrode (SRE)
* Standard potential is not exactly known.
* Potential is less reproducible and less stable.
* Calomel electrode is the most common SRE.
* Used for everyday laboratory measurements.
In easy words:
Primary reference electrodes are like the most accurate rulers, giving precise measurements. Secondary reference electrodes are like regular rulers, providing approximate measurements but are easier to use for daily tasks.